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Samarium – UV
and Visible Wavelength
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Samarium
- UV and Visible Wavelength
Description:
Samarium (III) oxide in perchloric acid.
Primary
Usage: Assessment of wavelength
scale accuracy in both UV and visible regions.
Useable
range:
230 nm to 560 nm, instruments with SBW of less than 5 nm.
Physical
Configuration: Far UV quartz
cells that have been permanently heat sealed.
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Product
Description:
Samarium perchlorate is a particularly suitable reference
material for checking the wavelength scale of a spectrophotometer over the
most commonly used range of 200 to 500 nm, as it has peaks throughout this
region. Many of the peaks are very narrow, providing very accurate location
of the peak wavelengths. With a half bandwidth of as little as 5 nm, some
peaks provide a very convenient way of checking instrument resolution also.
Shown below is this effect observed on the peak couple at 233-235 nm.
RM-SL:
Consists of one sealed
cell, with certified peak at spectral bandwidth values
of
0.10 nm, 0.25 nm, 0.50 nm, 1.00 nm, 1.50 nm, 2.00 nm and 3.00 nm. |
Typical
values obtained:
| SBW
|
nm |
nm |
nm |
nm |
nm |
nm |
nm |
nm |
nm |
nm |
nm |
nm |
nm |
nm |
| 0.10
|
479.18 |
463.49 |
415.20 |
401.45 |
390.60 |
374.27 |
362.36 |
346.96 |
332.09 |
317.59 |
305.28 |
290.24 |
278.99 |
235.27 |
| 0.25 |
479.17 |
463.48 |
415.33 |
401.41 |
390.68 |
374.24 |
362.55 |
344.61 |
331.94 |
317.71 |
305.30 |
290.29 |
279.07 |
235.18 |
| 0.50 |
479.12 |
463.44 |
415.32 |
401.40 |
390.51 |
374.32 |
362.42 |
344.61 |
331.94 |
317.60 |
305.38 |
290.19 |
278.96 |
235.16 |
| 1.00 |
478.99 |
463.53 |
415.44 |
401.36 |
390.61 |
374.31 |
362.46 |
344.51 |
332.05 |
317.58 |
305.23 |
290.22 |
279.10 |
235.21 |
| 1.50 |
479.07 |
463.60 |
415.65 |
401.28 |
390.55 |
374.31 |
362.53 |
344.48 |
332.14 |
317.49 |
305.32 |
290.20 |
279.10 |
235.21 |
| 2.00 |
478.86 |
463.71 |
415.99 |
401.27 |
390.54 |
374.22 |
362.32 |
344.57 |
332.09 |
317.52 |
305.56 |
290.20 |
279.10 |
235.038 |
| 3.00
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478.57 |
463.77 |
415.99 |
401.18 |
390.65 |
374.0 |
362.11 |
344.50 |
332.00 |
317.50 |
305.43 |
290.50 |
279.07 |
234.60 |
All
Starna®
samarium Certified Reference Materials are manufactured using procedures
similar to those used in the preparation of our Holmium Oxide Reference
Material (RM-HL). After filling under controlled conditions, the cells are
then permanently sealed by heat fusion and the values certified by the procedure
described below. |
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Calibration
procedure:
Traceability:
Primary
instrumental wavelength calibration is established using the emission
lines from mercury and deuterium sources.
Additional
traceability links to NIST primary materials are established using
SRM 2034 holmium oxide (4% m/v) in perchloric acid (10% v/v).
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Use:
All appropriate fundamental parameters and procedures
relating to measurement, handling and storage are fully documented
on the certificate supplied with each Certified Reference Material.
(see MSDS) |
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Cells
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materials other products
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